S. B. Khasare
Structural properties of liquid mixture related thermodynamic behavior in terms of liquid clusters are considered using third Khasare EOS for pure liquid. Unique solution is possible by evaluating????±z????± number of moles (the amount of participants in thermodynamic process).Number of moles seems to be a physical variable in present computations. Temperature range for all computations is set up from 293.16 K to a limit such that corresponding volume expansion coefficient for liquid mixture tends zero. The value of z-????±????±is attributed to variations in cluster size over entire mole fraction. Calculations are drawn on sample set of parametric equations in terms of temperature for ultrasonic wave velocity, density, and fairly constant a ratio of specific heat (1.3).
