Insights in Analytical Electrochemistry Open Access

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Commentary Article - (2022) Volume 8, Issue 6

The Analyte is Deposited by Electrochemical Reduction
Dariush Norouzian*
 
Department of Nanotechnology, Pasteur Institute of Iran, Iran
 
*Correspondence: Dariush Norouzian, Department of Nanotechnology, Pasteur Institute of Iran, Iran, Email:

Received: 01-Nov-2022, Manuscript No. IPAEI-22-15180; Editor assigned: 03-Nov-2022, Pre QC No. IPAEI-22-15180; Reviewed: 17-Nov-2022, QC No. IPAEI-22-15180; Revised: 22-Nov-2022, Manuscript No. IPAEI-22-15180; Published: 29-Nov-2022, DOI: 10.21767/2470-9867-8.6.27

Description

A technique known as electrogravimetry involves quantitatively electroplating a metal onto a platinum electrode. The difference in weight between the electrode before and after electroplating determines the amount of metal plated. A technique called electrogravimetry is used to separate and measure ions of a substance, typically a metal. The analyse solution is electrolyzed during this procedure. On the cathode, the analyse is deposited by electrochemical reduction. The product is weighed as a deposit on one of the electrodes in electrogravimetry. Coulombs are the unit of measurement used in coulometry to measure the amount of electricity required for electrolysis. Both approaches are very sensitive, quick, and accurate. A technique called electrogravimetry is used to separate and measure ions of a substance, typically a metal. The analyse solution is electrolyzed during this procedure. The difference between the cathode’s mass before and after the experiment is used to calculate the analyses mass in the original solution. To ensure that only the metal being analysed will be deposited on the electrode, it is essential to control its potential. The cycle is like electroplating. In electrolysis, polarization causes a back EMF, which lowers the actual EMF of the cell. As a result, the only way an electrolyte can be electrolyzed is to eliminate this back EMF. When two separate platinum electrodes are immersed in a dilute copper sulphate solution and a potential source is applied, the system will not experience any significant current until some minimum potential is applied, after which the current will increase as the applied potential increases. The applied voltage known as the decomposition potential is just enough to overcome the back EMF caused by polarization and also to cause the electrolysis of an electrolyte without any obstacles.

For a wide range of metals, whether present singly or in mixtures, electrogravimetry typically has a precision of a few parts per 1000, is relatively quick, and has a moderate sensitivity. Calibration is not necessary because deposit stoichiometry and relative atomic masses are used to calculate the analyse concentration from the quantity measured. Regardless of the charge required to effect its deposition, the mass of the deposited material is the measured. A reagent that can be used excessively is the electron. If competing reactions do not result in the code position of other materials or prevent the deposition of the necessary species, then a current efficiency of 100% is not required. Polymer research, copper electrode position, gold oxidation in an acidic medium, iron passivity in a sulphuric medium, and ionic insertion in WO3 are all examples of applications for electrogravimetry. Electrogravimetry is an electro analytical method in which the substance to be measured typically a metal is deposited on an electrode and weighed prior to and following the experiment. In order to guarantee that only the metal that can be determined will deposit the electrode’s potential needs to be carefully selected. Depending on how the assays are carried out, chemical analysis, which relies on the use of measurements, is divided into two categories. Wet chemical analysis, also known as classical analysis, is a subset of analytical methods that rely solely on a balance and no other mechanical or electronic instruments.

Acknowledgement

None.

Conflict Of Interest

The author’s declared that they have no conflict of interest.

Citation: Norouzian D (2022) The Analyte is Deposited by Electrochemical Reduction. Insights Anal Electrochem. 8:27.

Copyright: © 2022 Norouzian D. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.