B K Kang, M S Kim, J S Kim, Y W Chang and D H Kim
KITECH, Republic of South Korea Hanyang University, Republic of South Korea
Posters & Accepted Abstracts: Polym Sci
The higher silica content in the tire-tread rubber can maximize the efficiency of the vehicle. However, silica does not mix well with other mixtures, including the tire-tread rubber. This phenomenon deteriorates the various properties of the tire-tread rubber. Therefore, we have tried to improve the dispersity of silica in tire-tread rubber by using dispersant. The dispersion of silica in tire-tread styrene-butadiene rubber (SBR) is one of important factors in the mechanical properties of it. We prepared dispersants to enhance silica content and dispersity in SBR using wet master batch (WMB) system. The dispersants were prepared by copolymerization of styrene with allyl alcohol or methyl methacrylate. The synthetic conditions of dispersants were changed to improve the silica loading content and dispersity in WMB system for the preparation of silica-SBR composites. The WMB system was consisted of the steps involving dispersants synthesis, silica modification, dispersion of modified silica in SBR emulsion latex, and coagulation of silica-SBR composites. We confirmed the structure of the dispersants using FT-IR. The content of silica in the composites was measured by thermal gravimetric analysis (TGA) according to the types of dispersants. We also studied the payne effect with rubber process analyzer (RPA) instrument and dynamic viscoelasticity with Dynamic mechanical analysis (DMA) instrument. We measured the mechanical properties of them such as tensile strength and modulus of M300. We found the optimal types and content of dispersants for silica-SBR composites.
Recent Publications 1. Bourgeat Lami E, Espiard Ph and Guyot A (1995) Poly (ethyl acrylate) latexes encapsulating nanoparticles of silica: 1. functionalization and dispersion of silica. Polymer. 36.23:4385-4389. 2. Choi Sung Seen, Park Byung Ho and Song Hanjong (2004) Influence of filler type and content on properties of styreneâ?butadiene rubber (SBR) compound reinforced with carbon black or silica. Polymers for Advanced Technologies. 15.3:122-127. 3. Choi Sung Seen, Nah Changwoon and Jo Byung Wook (2003) Properties of natural rubber composites reinforced with silica or carbon black: influence of cure accelerator content and filler dispersion. Polymer International. 52.8:1382-1389. 4. Yan Gui et al. (2016) Preparation and performance of silica/SBR masterbatches with high silica loading by latex compounding method. Composites Part B: Engineering. 85:130-139 5. Byeongho Seo et al. (2013) Characterization of ANSBR/Silica compound with acrylonitrile as a polar group in SBR. Macromolecular Research. 21(7):738746.
Byeongkwan Kang is currently pursuing Master’s Degree in Chemical Engineering at Hanyang University, Republic of South Korea. He is also working at Korea Institute of Industrial Technology (KITECH). Our company research Institute of Industrial Technology Convergence leads Industry Convergence Technology and explores future growth engines to drive the economy by developing and commercializing intelligent robots, high-tech medical fibers, ultra-precision nanotechnology, wellness systems, and packaging technology. He is mainly interested in polymer chemistry such as hydrogel.
Email:90kbk@kitech.re.kr
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